Beilstein J. Org. Chem.2017,13, 855–862, doi:10.3762/bjoc.13.86
subsequent Vorbrüggen glycosylation, the protecting group could be removed smoothly in the presence of 5 mol % Ph3PAuOTf in dichloromethane to provide kipukasin A in high yield and regioselectivity.
Keywords: gold catalysis; kipukasin A; marinenucleoside; total synthesis; Vorbrüggen glycosylation